LightCell SUPERHEAVY — emission partition

300 GW methalox + NaCl ablation · chemiluminescent Na selective emitter · not thermal (no Planck/Wien ceiling) · verified Zig→WASM kernel

Operating point

free-Na density (m⁻³), log scale. From Cantera speciation.
kinetic T (K), methalox flame. Decoupled from excitation T.
path length (m), log. Sets 589 optical depth → imprisonment.

Chemiluminescent pump measured

frac of Na pumped to 3p by bond energy. Rate-matrix output (task #50).
frac pumped directly to 3d (819 upper).
chemi-ionization → drives free-bound/free-free continuum.
≈0 at flame T (Cantera: Na₂ ~2e-8). Tunable for cool zones.
incandescent-soot graybody loading. The broadband Na-D competes against. Drives selectivity hard — at fuel-rich loading the fireball is mostly continuum.

Spectral partition of radiated power

589 nm (3p→3s, trapped reservoir) 819 nm (3d→3p, escapes) other lines + Na₂ continuum (fb+ff)
in-band fraction (589+819) = device selectivity figure of merit
emergent spectrum — 589 self-reversal depth ∝ optical depth; 819 rides on top